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def main():
    #Intro
    print("Roulette Wheel Colors App...")
   

    #Prompt user for numbers (0-36)
    print("Please eneter pocket number(0-36)")

You have a custom function called main(), but you'll need to call it:

main()  # this will call the function

Or, simply do away with the function:

# Intro
print("Roulette Wheel Colors App...")

# Prompt user for numbers (0-36)
print("Please enter pocket number(0-36)")

dgizzly

rob101