creating dict out of CSV file without the headers

[Yoriz]

Cannot see the csv but please don't use pictures in the future just cut and pasted a sample of the csv.
As I said before you need to change your indexing to 1
you have

noc_dict = {}
line = 'AFG, Afghanistan'

line = line.replace('\n', '')
line = line.split(',')
noc_dict[line[0]] = line[1:]
print(noc_dict)

which will output

Output:
{'AFG': [' Afghanistan']}

because [1:] is a list of the 1 index and all the rest of the items if there are any

---

you just want to use 1 as the index to get the item on its own

noc_dict = {}
line = 'AFG, Afghanistan'

line = line.replace('\n', '')
line = line.split(',')
noc_dict[line[0]] = line[1]
print(noc_dict)

Output:
{'AFG': ' Afghanistan'}