Iteration with 2 Variables

[punksnotdead]

Hello, This is my first attempt at writing a program using Python and I'm a bit stuck.
I'd like to write the sequence shown in the comments to an Excel spreadsheet. I can do it for just one variable i but get an error (Value Error: Too many values to unpack (Expected 2) when i try to use a second variable j to create a nested loop.
Can anyone help? (Sorry I know this will seem really basic to some)

Here is the code:

import xlsxwriter

workbook = xlsxwriter.Workbook('MyTest.xlsx')
worksheet = workbook.add_worksheet()

row = 0
col = 0

for i,j in range(0,2),(0,2):

    worksheet.write(row, col, i)
    worksheet.write(row, col+1, j)

    row += 1

workbook.close()

#want output

Output:
#00
#01
#02
#10
#11
#12
#20
#21
#22