Script File Failure-Path Error?

[snippsat]

Your enviroment path variables look ok.
Open cmd and do this.

C:\>python -V
Python 3.10.5

C:\>pip -V
pip 22.3 from C:\python310\lib\site-packages\pip (python 3.10)
C:\>

For your this should work and point to Python 3.11.

The problem is that you most run it with whole file name include .py file extensions.
So like this.

C:\Users\jerry>python hello_world.py